Mean Amplitudes of Vibration of Chlorosyl Fluoride, FCIO
نویسنده
چکیده
Five of the six possible oxide fluorides of chlorine have been characterized. They range in stability from the thermally unstable chlorosyl fluoride, FCIO, to the chemically rather inert perchloryl fluoride, FC103 [1], FCIO is a very interesting molecule as it consists of a hypervalent chlorine atom bonded to the two most electronegative atoms, fluor and oxygen, in an angular, Cv-symmetry, arrangement. It can be obtained by controlled hydrolysis of C1F3 in a flow reactor or by photolysis of a mixture of C1F and 0 3 in an argon matrix [2].
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تاریخ انتشار 2013